Friday, 20 November 2015

      Mg(OH)2  → Mg+2   +  2OH-
              NH4+  is strong conjugate acid which attract OH- ions and convert to NH4OH
            2NH4+  +2 OH-  →2 NH4OH
            More Mg(OH)2 will ionize to provide OH- ions to NH4+
      2: hydroxides of Aluminium  Al (OH)3 
      Aluminium hydroxide, like aluminium oxide, is amphoteric - it has both basic and acidic properties. It is prepared by
      1: by the reaction of ammonium salt with alkali:
      Al2  (SO4 )3  +  6NH4OH   →3(NH4)2 SO4  +2 Al(OH)3
      2: By the hydrolysis of AlCl3 .
      AlCl3  + 3H2O → Al(OH)3  + 3HCl

      Other Hydroxides:
      The elements Si , P ,S and Cl of period 3 form hydroxides in which OH group is covalently bonded to these elements like Si(OH)4 , H3PO4 ,H2SO4 , HClO4 

      None of these contains hydroxide ions. In each case the -OH group is covalently bound to the Period 3 element, and in each case it is possible for the hydrogens on these -OH groups to be removed by a base. In other words, all of these compounds are acidic. 

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